If the supplier definitely exists in Dimensions, it is likely being excluded from FocalPoint because of a supplier filter.
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To check this:
Log in to FocalPoint Administrator
Browse to System Options > Purchasing > Purchase Requests Setup
Highlight the Purchase Request type you need to check and click Edit
On the General tab, find the Supplier Filter line - if this is set to anything other than "None" then there is a filter in place
Identify the field being used and the conditions (what is must equal or not equal) from this tab
Find the supplier record you were trying to use and update it to fit the filter conditions from the previous step
You should then be able to use the supplier on a Purchase Request
